Effect of Caliche Nodules on Soil Water Storage in the Northern Loess Plateau of China     

Tiexiong Gong  Yuanjun Zhu  Yunqiang Wang  Wei Hu  Ming'an Shao 《洁净——土壤、空气、水》2019,47(7)

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大洋多金属结核中铁锰质矿物拉曼光谱特征初探     

赖佩欣  任江波  邓剑锋 《矿床地质》2020,39(1):126-134

拉曼光谱是一种快速无损的分析手段,它既可观察样品的显微结构构造,也可分析样品的成分和结构。为了丰富多金属结核的岩石矿物学特征,文章对西太平洋某海山区的多金属结核样品进行了X射线粉末衍射分析和拉曼光谱分析。X射线分析结果显示该区域样品主要含有水羟锰矿、钡镁锰矿、斜长石、钙十字沸石和石英,显微构造主要有纹层状构造、柱状构造、树枝状构造、充填构造等。通过分析对比潮湿样品和烘干样品铁锰质矿物的拉曼特征谱峰,得出结核中水羟锰矿的特征谱峰位于490 cm~(-1)、570 cm~(-1)和626 cm~(-1)附近,钡镁锰矿的特征谱峰则位于640 cm~(-1)附近,与陆地上对应矿物的特征拉曼谱峰不同。结核中的钡镁锰矿结构不稳定,经过风干或者抛磨后部分产生相变,不同显微结构中,相变情况不同。经与RRUFF数据库比对,识别出钙十字沸石、斜长石等自形晶,多分布于结核最内层,往结核外层总体减少。矿物微晶多见铁锰质矿物微晶和钙十字沸石微晶,铁锰质矿物绕其向外生长。  相似文献   

大洋铁锰结核的微生物成矿过程及其研究进展   总被引：1，自引：1，他引：0  

姜明玉  胡艺豪  于心科  曹文瑞  萨仁高娃  常凤鸣 《海洋科学》2020,44(7):156-164

深海铁锰结核作为世界上潜在的巨大金属宝库已成为当今开发海底矿藏的热点，因而深入了解铁锰结核成矿过程成为其开发利用的先决条件。研究发现多金属铁锰结核中的铁锰矿物不仅仅是由单纯的物理作用形成的，同时也包含了海洋生物驱动的生物矿化的过程。本文介绍了运用分子生物学、矿物学和地球化学等多学科的研究方法对大洋中铁锰的生物成矿过程和成矿特征的研究。深海铁锰结核的生长速率缓慢且其生长演化伴随着微生物群落的活动，因此结核的生长过程同时也记录着不同时期微生物群落结构的变化并生成了大量的微生物化石。在铁和锰的生物矿化过程中，细菌可以通过酶促反应氧化Fe（Ⅱ）和Mn（Ⅱ），同时可能伴随生物能量的生成，此外微生物还可以通过非酶促反应的方式促进Fe和Mn的富集沉淀。这些研究表明生物矿化作用在大洋铁锰结核成矿过程中有巨大贡献，对大洋铁锰结核的生物成因过程提供更加全面准确的理解，从而为今后进一步充实大洋铁锰结核的生物矿化理论及其开发利用提供依据。  相似文献   

贵州遵义二叠纪锰矿气液喷口群的发现及地质意义   总被引：4，自引：4，他引：0       下载免费PDF全文

汪洋  刘志臣  陈登  钟月丽  秦先进 《贵州地质》2018,35(2):81-87,95

在通过对遵义市锰矿整装勘查区及周边所有探矿工程资料整理、分析研究的基础上,结合野外大比例尺专项地质填图、剖面实测和测试的成果。将贵州遵义二叠系锰矿与华南古天然气渗漏沉积型锰矿床成矿理论进行详细对比,认为遵义锰矿总体是"内生外成",成锰物质主体来自地幔,遵义锰矿属"古天然气渗漏沉积型锰矿床",借鉴古天然气渗漏沉积型锰矿床的成矿理论和研究方法,运用遵义锰矿裂陷槽盆地结构的划分、同沉积断裂的识别和中心相、过渡相和边缘相判别标志,在断陷盆地中喷溢口及附近,发现矿石及其顶底板具有古天然气渗漏沉积型锰矿床独有的结构构造、同位素、生物组合等特征。研究认为遵义成锰盆地至少存在5个气液渗漏喷溢口,分布于Ⅲ级断陷盆地内,每一个喷溢口构成一个相对独立的气液渗漏喷溢沉积成矿系统,遵义锰矿床是形成由若干个气液渗漏喷溢沉积成矿子系统构成的沉积成矿系统。贵州遵义二叠纪锰矿成矿的气液渗漏喷溢口的发现,对遵义锰矿"内生外成"成因研究提供了宏观地质证据,为建立深部锰矿找矿预测模型提供了重要依据,为研究遵义锰矿的古天然气渗漏沉积型锰矿床成矿系统具有重要意义。  相似文献   

贵州二叠系茅口组顶部锰矿沉积特征及矿床成因研究   总被引：4，自引：0，他引：4  

杨瑞东  程玛莉  高军波  徐海  李军  陈军  刘坤 《地质学报》2018,92(4):804-816

通过对遵义、纳雍营盘等地含锰岩系沉积特征及沉积地球化学特征研究,结果表明,锰矿体形态主要以层状、似层状、透镜状、脉状产出,具有角砾状构造、递变层理等,常夹硅质岩和凝灰岩,具有热水喷流沉积构造特征。锰矿层位于玄武岩之下,夹于茅口组灰岩顶部,说明锰矿成矿在玄武岩喷发之前。含锰岩系中的矿物组合有浸染状黄铜矿,黄铁矿,重晶石,天青石,菱锰矿、钙菱锰矿、锰方解石、黄铜矿、蓝铜矿、褐铁矿、绿泥石、石英及其他碳酸盐岩矿物等,这些矿物组合与热水沉积矿物组合类似。对含锰岩系进行微量元素、稀土元素、碳同位素分析测试表明,含锰岩系富集As、Co、Cu、Cr、Mo、Ni、Pb、U和V等元素,Fe/Ti、(Fe+Mn)/Ti及Al/(Al+Fe+Mn)比值,Fe-Mn-(Cu+Co+Ni)×10三角图解等均显示锰矿属于热水沉积成因。锰矿石碳同位素值δ~(13) C介于+4.17‰~-18.53‰,氧同位素δ~(18) O介于-6.98‰~-10.05‰显示,碳同位素组成具有热水沉积特征。含锰岩系稀土配分曲线与峨眉山玄武岩稀土配分曲线类似,表明锰矿成矿物质来源与峨眉地幔热柱密切相关。  相似文献   

Origin and variability of resource-grade marine ferromanganese nodules and crusts in the Pacific Ocean: A review of biogeochemical and physical controls     

Philomène A. Verlaan  David S. Cronan 《Chemie der Erde / Geochemistry》2022,82(1):125741

Marine ferromanganese nodules and crusts containing Mn, Cu, Ni and Co in the most promising resource-grade concentrations and quantities, together with Fe and Zn (all elements of biogeochemical importance) are found far from land on the deep seafloor of the Pacific Ocean. The biogeochemical, chemical and physical mechanisms contributing to their formation, distribution, abundance and – for these six elements – variability in their concentrations in these deposits, are the main focus of the present review. The mechanisms addressed include biological productivity, sedimentation types and rates, bottom water characteristics, the Calcium Carbonate Compensation Depth, the depth and intensity of the oxygen minimum zone, and biogeochemical characteristics of the six focal elements. Particular attention is given to comparisons between the deposits found in the north and the south Pacific, in order to present an overarching view of our current understanding of the mechanisms that apply to both nodules and crusts in both oceanic hemispheres, including examination of the possible existence of a marine ferromanganese oxide continuum. The renewed interest in the commercial exploitation of these deposits has stimulated a welcome increase in scientific research that is essential to informing the public discourse on seabed mining. We briefly reflect on the work addressed in this review in that context.  相似文献   

鄂尔多斯盆地上三叠统延长组长7段富有机质页岩中藻类化石的发现及地质意义     

袁伟  柳广弟  袁红旗 《地质论评》2023,69(1):365-374

鄂尔多斯盆地上三叠统延长组长7段富有机质页岩是该盆地中生界含油系统的主力烃源岩,其有机质丰度高,类型好,具有巨大的生烃潜力。该套烃源岩中有机质的富集很大程度上取决于长7期的高古生产力及其提供的充足的有机质。长7期藻类勃发的存在已被多数学者所接受,但是目前还缺乏直观、有力的证据。笔者等通过薄片和扫描电镜观察、能谱分析,在长7段的脉状黄铁矿附近和碳酸盐结核中发现了属种单一、分布丰度高的藻类化石,它们呈现出近似球状的轮廓,在中部分布着一条裂缝。这些藻类化石的发现具有重要的地质意义,它为长7期的藻类勃发提供了很好的证据,也为该时期热液活动的重要作用提供了有力的支撑。  相似文献   

Detrital and authigenic(?) baddeleyite (ZrO2) in ferromanganese nodules of Central Indian Ocean Basin     

Bibhuranjan Nayak  Swapan Kumar Das  Kalyan Kumar Bhattacharyya 《地学前缘(英文版)》2011,2(4):571-576

Occurrence of baddeleyite (ZrO2) which is a rare mineral has been recorded in ferromanganese nodules of Central Indian Ocean Basin (CIOB). The mineral occurs either as independent isolated sub-rounded to elliptical grains or in clusters forming fine subhedral crystals (<3 mm) within ferromanganese concretionary growth bands. The mode of occurrence, textural features and chemistry of the mineral suggest detrital and possibly an authigenic origin for baddeleyite. For authigenic origin it is proposed that zirconium might have got released either from the terrigenous sediments or the altered seafloor rocks forming halogen complexes and subsequently it has re-precipitated in the form of baddeleyite within manganese nodules under oxic to sub-oxic conditions.  相似文献   

Evaporation Process in Soil Surface Containing Calcic Nodules on the Northern Loess Plateau of China by Simulated Experiments     

Yuanjun Zhu  Ming'an Shao  Hongbo Shao 《洁净——土壤、空气、水》2009,37(11):866-871

Soil containing calcic nodules is widely present on the northern Loess Plateau of China owing to soil genesis under local climate conditions. In most studies, little attention is payed to the effect of calcic nodules on soil evaporation and ecoenvironment, resulting in inaccurate evaporation estimation in this kind of soil and further improper field water management measures and irrigation effects. In this paper, soil column experiments were conducted in order to investigate evaporation process in soil containing calcic nodules and the effect of calcic nodules on soil evaporation was determined. The results indicated that evaporation reduction was positively related to calcic nodule content (CNC = mass of calcic nodules/total mass), and could be estimated by the experiential equation: E_soil = E₀ (1 – 0.4 CNC) (E_soil = actual evaporation, E₀ = theory evaporation in soil without calcic nodules). When CNC was below 0.2, the impact could be neglected. While, as CNC exceeded 0.2, the impact needed to be considered during soil evaporation estimation. As CNC reached 0.5, soil evaporation could be reduced by 7.5 mm, accounting for around 10% of the total soil water. Water balance calculation in soil columns showed that water absorbed by calcic nodules was partially available to evaporation. Water available to evaporation was positively related to CNC, and this water could not exceed 63% of the water absorbed by calcic nodules. Generally, evaporation behavior was dominated by calcic nodule quantity and its water absorption. These results provide new ideas for irrigation measures in arid areas of the globe.  相似文献   

Geochemical Characteristics and Genetic Significance of Datangpo‐Type Manganese Ore Deposits during the Cryogenian Period     

Jiafei Xiao  Jingyang He  Haiying Yang  Chengquan Wu  Jianbin Xu  Yantao Li 《Resource Geology》2019,69(3):227-248

The Datangpo‐type manganese ore deposits, which formed during the Nanhuan (Cryogenian) period and are located in northeastern Guizhou and adjacent areas, are one of the most important manganese resources in China, showing good prospecting potential. Many middle‐to‐large deposits, and even super‐large mineral deposits, have been discovered. However, the genesis of manganese ore deposits is still controversial and remains a long‐standing source of debate; there are several viewpoints including biogenesis, hydrothermal sedimentation, gravity flows, cold‐spring carbonates, etc. Geochemical data from several manganese ore deposits show that there are positive correlations between Al₂O₃ and TiO₂, SiO₂, K₂O, and Na₂O, and strong negative correlations between Al₂O₃ and CaO, MgO, and MnO in black shales and manganese ores. U, Mo, and V show distinct enrichment in black shales and inconspicuous enrichment in Mn ores. Ba and Rb show strong positive correlations with K₂O in manganese ores. Cu, Ni, and Zn show clear correlations with total iron in both manganese ores and black shales. ∑REE of manganese ores has a large range with evident positive Ce anomalies and positive Eu anomalies. The Post Archean Australian Shale (PAAS) normalized rare earth element (REE) distribution patterns of manganese ores present pronounced middle rare earth element (MREE) enrichment, producing “hat‐shaped” REE plots. ∑REE of black shales is more variable compared with PAAS, and the PAAS‐normalized REE distribution patterns appear as “flat‐shaped” REE plots, lacking evident anomaly characteristics. δ¹³C values of carbonate in both manganese ores and the black shales show observable negative excursions. The comprehensive analysis suggests that the black shales formed in a reducing and quiet water column, while the manganese ores formed in oxic muddy seawater, which resulted from periodic transgressions. There was an oxidation–reduction cycle of manganese between the top water body and the bottom water body caused by the transgressions during the early Datangpo, which resulted in the dissolution of manganese. Through the exchange of the euphotic zone water and the bottom water, and episodic inflow of oxygenated water, the manganese in the bottom water was oxidized to Mn‐oxyhydroxides and rapidly buried along with algae. In the early diagenetic stage, Mn‐oxyhydroxides were reduced and dissolved in the anoxic pore water and then transformed into Mn‐carbonates by reacting with HCO₃^? from the degradation of organic matter or from seawater. In the intervals between transgressions, continuous supplies of terrigenous clastics and the high productive rates of organic matter in the euphotic zone resulted in the deposition of the black shales enriched in organic matter.  相似文献